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21.
We measured the amount of arsenic, chromium, copper, lead, nickel, vanadium, and zinc accumulated over a five-year period
from 1997 to 2002 in surface sediments of seven salt marshes along the New Brunswick coast of the Bay of Fundy, Canada. Study
sites extended from outer to inner Bay, spanning a gradient in tidal range (6–12 m) and mean sediment deposition rate (0.27–1.76
cm yr−1). In each study site, metal concentrations were measured in low and high marsh areas. Concentrations of chromium, nickel,
and zinc appear to be within their natural range, while arsenic, lead, and vanadium are enriched in some sites. Calculated
sediment metal loadings rates showed variability among marsh sites that closely followed sediment deposition patterns, suggesting
sediment deposition rate is the driving factor of short-term metal accumulation in Fundy marshes. The value of salt marshes
as a sink for metals may be enhanced by high sedimentation rates. 相似文献
22.
A model describing the three‐dimensional matrix flow along a slope with rock fragments or impermeable blocks was developed. The model was combined with modified Picard's iteration to ensure mass conservation in the unsaturated flow. We found that rock fragments obstruct water flow along the slope. The groundwater table must be raised to provide a sufficient pore water pressure gradient to facilitate water flow, but higher pore water pressure may induce slope failure. We also conducted a bench‐scale laboratory flume experiment to examine the effects of impermeable blocks on downstream seepage flow. In addition, a numerical experiment was conducted to examine how different arrangements of impermeable blocks affect downstream seepage flow and pore water pressure. This research demonstrated that the hydraulic phenomena were affected when impermeable blocks were present, and pore water pressure increased as the position of impermeable blocks was lowered. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
23.
Since the early 1990s, there has been an active program in Hong Kong to manage and protect local populations of small cetaceans from the effects of massive development in the area. This paper reviews the progress that has been made. Only two species regularly occur there: the Indo-Pacific humpback dolphin and the finless porpoise. Because most development has occurred in the western waters of Hong Kong, where generally only the humpback dolphin occurs, most of the work has been conducted on that species. Development of large infrastructure projects (such as airports, bridges, expressways, power plants, fuel facilities, and container ports) in Hong Kong often results in land reclamation, dredging and dumping of spoils, pipe and cable laying, percussive and bored piling work, underwater blasting, large increases in vessel traffic, and other impacts. Several mitigation measures have been used with varying levels of success, including bubble curtains/jackets, exclusion zones, ramping up of piling hammers, acoustic decoupling of noisy equipment, vessel speed limits, no-dumping policies, and silt curtains. Baseline, construction-phase, and operational-phase cetacean monitoring is often conducted to evaluate the success of conservation measures put into place. The Environmental Impact Assessment process in Hong Kong has involved cetaceans to a degree perhaps higher than anywhere else in the world, and much can be learned from studying the successes and failures of this situation. 相似文献
24.
25.
Dieke Postma Søren Jessen Mai Thanh Duc Pham Hung Viet Flemming Larsen 《Geochimica et cosmochimica acta》2010,74(12):3367-508
Sediments from the Red River and from an adjacent floodplain aquifer were investigated with respect to the speciation of Fe and As in the solid phase, to trace the diagenetic changes in the river sediment upon burial into young aquifers, and the related mechanisms of arsenic release to the groundwater. Goethite with subordinate amounts of hematite were, using Mössbauer spectroscopy, identified as the iron oxide minerals present in both types of sediment. The release kinetics of Fe, As, Mn and PO4 from the sediment were investigated in leaching experiments with HCl and 10 mM ascorbic acid, both at pH 3. From the river sediments, most of the Fe and As was mobilized by reductive dissolution with ascorbic acid while HCl released very little Fe and As. This suggests As to be associated with an Fe-oxide phase. For oxidized aquifer sediment most Fe was mobilized by ascorbic acid but here not much As was released. However, the reduced aquifer sediments contained a large pool of Fe(II) and As that is readily leached by HCl, probably derived from an unidentified authigenic Fe(II)-containing mineral which incorporates As as well. Extraction with ascorbic acid indicates that the river sediments contain both As(V) and As(III), while the reduced aquifer sediment almost exclusively releases As(III). The difference in the amount of Fe(II) leached from river and oxidized aquifer sediments by ascorbic acid and HCl, was attributed to reductive dissolution of Fe(III). The reactivity of this pool of Fe(III) was quantified by a rate law and compared to that of synthetic iron oxides. In the river mud, Fe(III) had a reactivity close to that of ferrihydrite, while the river sand and oxidized aquifer sediment exhibited a reactivity ranging from lepidocrocite or poorly crystalline goethite to hematite. Mineralogy by itself appears to be a poor predictor of the iron oxide reactivity in natural samples using the reactivity of synthetic Fe-oxides as a reference. Sediments were incubated, both unamended and with acetate added, and monitored for up to 2 months. The river mud showed the fastest release of both Fe and As, while the effect of acetate addition was minor. This suggests that the presence of reactive organic carbon is not rate limiting. In the case of the river and aquifer sediments, the release of Fe and As was always stimulated by acetate addition and here reactive organic carbon was clearly the rate limiting factor. The reduced aquifer sediment apparently can sustain slower but prolonged microbially-driven release of As. The highly reactive pools of Fe(III) and As in the river mud could be due to reoxidation of As and Fe contained in the reducing groundwater from the floodplain aquifers that are discharging into the river. Deposition of the suspended mud on the floodplain during high river stages is proposed to be a major flux of As onto the floodplain and into the underlying aquifers. 相似文献
26.
辉钼矿Re-Os同位素定年方法的改进与应用 总被引:13,自引:9,他引:4
公认的Re-Os同位素定年代表物辉钼矿,目前已在金属硫化物矿床年代学研究领域获得了广泛的应用。本研究采用浓HNO3分解辉钼矿样品,大大地简化了Re和Os的化学制备过程,并根据辉钼矿中正常Os含量水平相对放射成因187Os可以忽略的特点,以正常Os标准为稀释剂,实现了仪器测量过程中Os同位素质量分馏的在线校正,改善了分析数据的质量。该方法经辉钼矿国家标准物质进行验证,获得了满意的Re、Os含量及Re-Os年龄数据,并且在南岭地区与连阳复式岩体相关的姓坪夕卡岩型钼矿床成矿年龄研究中获得了成功应用。在实际应用中,为了获得有意义的能反映真实地质事件的年龄数据,辉钼矿样品不仅要有足够的取样量,而且还要保证粒度细、混合均匀。 相似文献
27.
P.A. Balykin G.V. Polyakov A.E. Izokh Tran Trong Hoa Ngo Thi Phuong Tran Quoc Hung T.E. Petrova 《Russian Geology and Geophysics》2010,51(6):611-624
The Jinping–Song Da rift structure in the Emeishan Large Igneous Province is composed of Permian high- and low-Ti volcanic and volcanoplutonic ultramafic-mafic associations of different compositions and genesis. High-Ti picrites, picrobasalts, basalts, and dolerites are enriched in LREE and depleted in HREE and show low Al2O3/TiO2 ratios (~4), commensurate εNd(T) values (+0.5 to +1.1), and low (Th/Nb)PM ratios similar to those of OIB-enriched mantle source. The established geochemical characteristics evidence that the parental melts of these rocks were generated from garnet lherzolite at the depths of garnet stability (~200 to 400 km). Later, high-Mg low-Ti volcanics (komatiites, komatiitic basalts, and basalts) and associating small peridotite-gabbro massifs and komatiite-basalt dikes were produced as a result of ~20% partial melting of depleted water-poor (≤0.03 wt.% H2O) peridotite substratum from the hottest upper part of mantle plume at relatively shallow depths (100–120 km). The LREE-depleted komatiites and komatiitic basalts are characterized by low (Ce/Yb)CH values, 187Re/188Os = 0.05–1.2, 87Sr/86Sr = 0.704–0.706, positive εNd(T) values (+3 to +8), γOs = –0.5 to +0.9, and strong negative anomalies of Ba, K, and Sr on the spidergrams. The scarcer LREE-enriched komatiites, komatiitic basalts, and basalts vary greatly in chemical composition and values of εNd(t) (+6.4 to –10.2), 87Sr/86Sr (0.706–0.712), and γOs (+14.8 to +56), which is due to the different degrees of crustal contamination of parental magmas. The Rb-Sr isotopic age of basaltic komatiite is 257 ± 24 Ma. The Re-Os age determined by analysis of 12 komatiite samples is 270 ± 21 Ma. These data agree with the age of flood basalts of the Emeishan Large Igneous Province. The komatiite-basalt complex of the Song Da rift is still the only Phanerozoic PGE-Cu-Ni-complex of this composition. The geochemistry of accompanying Cu-Ni-PGE-ores confirms their relationship with komatiite-basaltic magmatism. 相似文献
28.
Wei-Chia Hung Cheinway Hwang Chung-Pai Chang Jiun-Yee Yen Chih-Hsi Liu Wan-Huei Yang 《Environmental Earth Sciences》2010,59(7):1535-1548
During 1992–2007, excessive pumping of groundwater caused large-scale aquifer-system compaction and land subsidence in the
Choshui River Alluvial Fan, especially in the area of Yunlin county. The subsidence impedes surface-water runoff and endangers
the operation of Taiwan High Speed Rail. Leveling, Global Positioning System (GPS), multi-level compaction monitoring well,
and Differential Interferometric Synthetic Aperture Radar (DInSAR) are used to study the extent of subsidence in Yunlin and
its mechanism. These sensors complement each other in spatial and temporal resolutions. A leveling network totaling 434 km
in length was deployed to derive subsidence at every 1.5 km along the routes, and the result is accurate to few mm and shows
a basin-like subsidence pattern centering at Tuku Township. Four multi-level compaction monitoring wells, co-located with
GPS pillars, detect compactions at different depths, showing that the aquifer-system compaction (the cause of subsidence)
occurs mostly below depths >200 m, where reduction of groundwater pumping is most needed. The vertical displacements from
GPS and leveling agree to within 1 cm, and are larger than the cumulative compaction detected by the compaction-monitoring
wells, suggesting that compaction also occurs below 300 m (the depth of the wells). The vertical displacements derived using
DInSAR and 8 ENVISAT SAR images agree with the leveling result to 1–2 cm. 相似文献
29.
Nguyen Nghia Hung José Miguel Delgado Vo Khac Tri Le Manh Hung Bruno Merz András Bárdossy Heiko Apel 《水文研究》2012,26(5):674-686
The Mekong Delta is one of the largest and most intensively used estuaries in the world. Each year it witnesses widespread flooding which is both the basis of the livelihood for more than 17 million people but also the major hazard. Therefore, a thorough understanding of the hydrologic and hydraulic features is urgently required for various planning purposes. While the general causes and characteristics of the annual floods are understood, the inundation dynamics in the floodplains in Vietnam which are highly controlled by dikes and other control structures have not been investigated in depth. Especially, quantitative analyses are lacking, mainly due to scarce data about the inundation processes in the floodplains. Therefore, a comprehensive monitoring scheme for channel and floodplain inundation was established in a study area in the Plain of Reeds in the northeastern part of the Vietnamese Delta. This in situ data collection was complemented by a series of high‐resolution inundation maps derived from the TerraSAR‐X satellite for the flood seasons 2008 and 2009. Hence, the inundation dynamics in the channels and floodplains, and the interaction between channels and floodplains, could be quantified for the first time. The study identifies the strong human interference which is governed by flood protection levels, cropping patterns and communal water management. In addition, we examine the tidal influence on the inundation in various parts of the Delta, since it is expected that climate change‐induced sea level rise will increase the tidal contribution to floodplain inundation. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
30.
从精密工程测量的定义出发,指出其测量的特点,对精密工程测量的仪器如:马达全站仪、激光跟踪测量系统、数字摄影测量系统、测量机人和高程测量系统的发展和应用进行介绍;引用了某大堤作为工程实例,指出了在数据处理中利用自由网拟稳平差的优点,以及对它的适用性和网形布局对它的影响程度做了讨论. 相似文献